Evolutionary Algorithm based on State-space model (SEA) is a novel real-coded evolutionary algorithm, it has good optimization effects in engineering optimization problems. Global convergence of crossover SEA (SCEA) was studied to promote the theory and application research of SEA. The conclusion that SCEA is not global convergent was drawn. Modified Crossover Evolutionary Algorithm based on State-space Model (SMCEA) was presented by changing the comstruction way of state evolution matrix and introducing elastic search operation. SMCEA is global convergent was proved by homogeneous finite Markov chain. By using two test functions to experimental analysis, the results show that the SMCEA are improved substantially in such aspects as convergence rate, ability of reaching the optimal value and operation time. Then, the effectiveness of SMCEA is proved and that SMCEA is better than Genetic Algorithm (GA) and SCEA was concluded.